DOCXMicrosoft Word Open XML Document
Docx is well-known format for Microsoft Word documents. Introduced from 2007 with the release of Microsoft Office 2007, the structure of this new Document format was changed from plain binary to a combination of XML and binary files. Docx files can be opened with Word 2007 and lateral versions but not with the earlier versions of MS Word which support DOC file extensions.
Portable Document Format (PDF) is a type of document created by Adobe back in 1990s. The purpose of this file format was to introduce a standard for representation of documents and other reference material in a format that is independent of application software, hardware as well as Operating System. PDF files can be opened in Adobe Acrobat Reader/Writer as well in most modern browsers like Chrome, Safari, Firefox via extensions/plug-ins.