OSTOutlook Offline Storage File
OST or Offline Storage Files represent user's mailbox data in offline mode on local machine upon registration with Exchange Server using Microsoft Outlook. It is automatically created on the first use of Microsoft Outlook upon connectivity with server. Once the file is created, the data is synchronized with the email server so that it is available offline as well in case of disconnectivity from email server.
PSTPersonal Storage File
Files with .PST extension represent Outlook Personal Storage Files (also called Personal Storage Table) that store variety of user information. User information is stored in folders of different types that include emails, calendar items, notes, contacts, and several other file formats. PST files are used for archiving emailing data offline that can be later loaded and viewed in various applications.